Nitrates of both group 1 and group 2 metals are soluble in water. In fact, these metals can precipitate from their salt solutions as carbonates.Nitrates: Thermal stabilityNitrates of alkali metals,except LiNO3, decompose on strong heating forming nitrites and oxygen. so, the correct order of thermal stability of given carbonates is: BeCO 3 < MgCO 3 < CaCO 3 < K 2 CO 3 Be, Mg and Ca present in second group and K present in the first group. * Due to same reason, carbonates of group-1 are more stable than those of group-2. The effect of heat on the Group 2 carbonates. (You wouldn't see the oxygen also produced). for example,2KNO3 -> 2KNO2 +O2Nitrates of alkaline-earth … It describes and explains how the thermal stability of the compounds changes as you go down the Group. So C s 2 C O 3 has the highest thermal stability than the other given carbonates. The respective TG- and DSC-curves are represented. The hydroxides of the Group II metals, which may be used in thermochemical water-splitting cycles, have been investigated thermoanalytically. The thermal stability of the hydrogencarbonates. The thermal stability … Explanation: New questions in Chemistry. To test what you've learned from this lesson- Answer to question 23 the calcium ion has a larger charge (2+) thatn the potassium ion (1+). A higher temperature is required to decompose Ba(NO 3) 2 as compared to Mg(NO 3) 2. Beryllium carbonate decomposing most easily. (ii) Carbonates. The Facts The effect of heat on the Group 2 carbonates All the carbonates in this Group undergo thermal decomposition to give the metal oxide and carbon dioxide gas. All of these carbonates are white solids, and the oxides that are produced are also white solids. All the carbonates decompose on heating to give carbon dioxide and the oxide. Decomposition temperatures and decomposition enthalpies of the four hydroxides increase with increasing atomic weight of the compounds. b) lower c) A white solid producing a brown gas and leaving a white solid. Also, does thermal stability increase or decrease as you go down group 1 (with explanation please)? The larger compounds further down require more heat than the lighter compounds in order to decompose. Thank you This decreases the charge density and the ability of the cation to polarize the anion. However, carbonate of lithium, when heated, decomposes to form lithium oxide. I undergo less corrosioncompared to iron. Even for hydroxides we have the same observations. I know stability increases as you go down group 2, please explain why in language a good A level student can understand. Beryllium carbonate is unstable and can be kept only in the atmosphere of CO2. In all cases, for a particular set of e.g. Small highly charged positive ions distort the electron cloud of the anion. Correct order of stability of group 2a metal carbonates is 1 See answer mohitrathimr4440 is waiting for your help. Also, why does thermal stability increase down Group 2? All these carbonates decompose on heating to give CO 2 and metal oxide. MgCO 3(s) MgO(s) + CO 2(g) Thermal decomposition is defined as the use of heat to break down a reactant into more than one product Group 2 carbonates … Asked by Wiki User. Both carbonates and nitrates of Group 2 elements become more thermally stable down the group. Wiki User Answered . All the carbonates in this group undergo thermal decomposition to the metal oxide and carbon dioxide gas. As we move down group 1 and group 2, the thermal stability of nitrate increases. If "X" represents any one of the elements: As you go down the Group, the carbonates have to be heated more strongly before they will decompose 1. rihu27 rihu27 Answer: down the group the stability of metellic carbonates imcreass. They both have the same number of electrons is their outer shell, but Calcium is further down the group so I would have thought that Calcium is less thermally stable. The stability of the metal carbonates can be related to the reactivity series of metals. Can you please explain as simply as possible. Add your answer and earn points. Let's use MgCO 3 as an example. As we go down the group, the carbonates have to be heated more strongly before they will decompose. Charge Density and Polarising Power of Group 2 Metal Cations. BeCO 3 ⇌ BeO + CO 2. The amount of heat required for the drying procedure of … THERMAL STABILITY of OH Down Group II help with organic chem AS show 10 more Edexcel (IAL) Unit 2 Chemistry June 10th Thermal stability of carbonates down Group II thermal decomposition of group 2 carbonates Organic chem help! Thanks in advance x As we go down the group the stability of metal carbonates increases. The solubility of carbonates in water decreases as the atomic number of the metal ion increases. Decomposition becomes more difficult and thermal stability increases. Upon heating, carbonates decompose into oxide and carbon dioxide ; The thermal stability of group-1 and group-2 carbonates increase down the group. MgCO3 decomposes at 540 C. CaCO3 decomposes at 900 C. SrCO3 decomposes at 1290 C. BaCO3 decomposes at 1360 C. This is because of the increasing size of the cation (ionised metal) as we go down the group. Whereas bicarbonates give carbonate, water and carbon dioxide. The thermal stability; of these carbonates increases down the group, i.e., from Be to Ba, BeCO 3 < MgCO 3 < CaCO 3 < SrCO 3 < BaCO 3 BeCO 3 is unstable to the extent that it is stable only in atmosphere of CO 2. The carbonate ion has a big ionic radius so it is easily polarized by a small, highly charged cation. GROUP 2: THERMAL STABILITY OF THE CARBONATES AND NITRATES 1. a) Both barium carbonate and barium oxide (the product) are white. Why is Magnesium less thermally stable compared to Calcium? 2. All the Group 2 carbonates and their resulting oxides exist as white solids. Stability of oxides decreases down the group. Thermal decomposition is the term given to splitting up a compound by heating it. This is because the cation size increases down the Group, this reduces the charge density and polarising power of cation. 3. Thermal stability of Group II nitrates increases down the This is because the cation size increases down the Group, this reduces the charge density and polarising power of cation. All the carbonates in this group undergo thermal decomposition to the metal oxide and carbon dioxide gas. Any attempt to get them out of solution causes them to decompose to give the carbonate, carbon dioxide and water. The larger compounds further down require more heat than the lighter compounds in order to decompose. It describes and explains how the thermal stability of the compounds changes as you go down the Group. Group-2 carbonates are fairly soluble in the solution of CO 2; Thermal Stability. 2) Thermal stability of Group II nitrates increases down the Group. MCO 3(s) → MO (s) + CO 2(g) Where M is a Group II element. Carbonate Structure. Thermal decomposition is the term given to splitting up a compound by heating it. It means the stability increases from M g C O 3 to B a C O 3 . 6. Stability of carbonates increases down group I (alkali) and group II (alkaline earth) metals. (ii) All the alkaline earth metals form oxides of formula MO. Stability increases down the Group. Thermal stability of carbonates increases in a group as we move from top to bottom and decreases in a period as we move from left to right. 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